[rac-2-(1-Aminoethyl)phenyl-κ2C1,N](ethylendiamine-κ2N,N′)palladium(II) 3-methylbenzoate monohydrate
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چکیده
منابع مشابه
1-(2-Carboxyethyl)-3-(carboxylatomethyl)-2-ethylbenzimidazol-1-ium monohydrate
In the title compound, C14H16N2O4·H2O, three substituent groups are located on the same side of the benzimidazole ring plane. In the crystal, O-H⋯O hydrogen bonds and π-π stacking between parallel imidazole rings [centroid-centroid distance = 3.858 (4) Å] link the mol-ecules into a three-dimensional supra-molecular structure.
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The title compound, C(11)H(7)NO(4)·H(2)O, contains a 3-carb-oxy-quinolin-1-ium-2-carboxyl-ate (qda) zwitterion and one water mol-ecule. In the crystal, pairs of N-H⋯O hydrogen bonds link the mol-ecules into inversion dimers, and these dimers are further connected by O-H⋯O hydrogen bonds into a three-dimensional supra-molecular architecture. In addition, π-π inter-actions occur between pyridine ...
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In the title compound, C(8)H(12)N(2)O(3)S·H(2)O, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds and weak C-H⋯O inter-actions, which form R(1) (2)(6) and R(2) (2)(12) ring motifs, link the components into a three-dimensional network.
متن کامل[rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N′)palladium(II) 3-methylbenzoate monohydrate
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methyl-benzoate anion and the hydrate water mol-ecule are inter-connected by N-H⋯O and O-H⋯O ...
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The title compound, C(9)H(10)N(2)O(4)·H(2)O, was obtained as a zwitterion derived from the nucleophilic attack of 3-amino-pyridine on the fumaric α,β-system. Within the molecule, the amino-pyridine moiety and the carboxyl-ate and carb-oxy-lic acid fragments form dihedral angles of 68.6 (2) and 62.8 (2)°, respectively. The geometry adopted by the mol-ecule does not allow the formation of centros...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810028370